?[SO-PROPYL FORMATE HYDROLYSIS IN WATER AND THE EVALUATION OF RATE CONSTANTS

Authors

  • Shakila Begum PCSIR Laboratories, Jamrud Road, Peshawar-25120, Pakistan
  • Mohammad Aurang Zebb National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawae, Pakistan
  • Mohammad Ilyass National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawae, Pakistan

Keywords:

Esters, Hydrolysis, Rate constant, Iso-propyl formate.

Abstract

Emphasis has been placed on the data for the hydrolysis of Iso-propyl formate in neutral medium over the tempera-
ture range 303-343 K to illustrate the method, employing numerical integration and the criteria of least squares, for
the evaluation of the first and the second order rate constants in Kirmann's equation by the sum of trapezoids. The
values obtained for the second order rate constant k, (1mol" see:') are compared with the values reported in the
literature. The hydrolysis of iso-propyl formate involves alkyl-oxygen cleavage. A mini computer program on a
6502 12K, Acorn Atom computer has been designed for the evaluation of rate constants.

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Published

2000-04-24

How to Cite

Begum, S., Zebb, M. A., & Ilyass, M. (2000). ?[SO-PROPYL FORMATE HYDROLYSIS IN WATER AND THE EVALUATION OF RATE CONSTANTS. Biological Sciences - PJSIR, 43(2), 90–94. Retrieved from http://biostaging.pjsir.org/index.php/biological-sciences/article/view/2000

Issue

Vol. 43 No. 2 (2000): Pakistan Journal of Scientific and Industrial Research

Section

Articles